Evaluated Gas Phase Basicities and Proton Affinities of Molecules : An Update

Book Id: WPLBN0000659911
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Title:	Evaluated Gas Phase Basicities and Proton Affinities of Molecules : An Update
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Language:	English
Subject:	Technology., Reference materials, Technology and literature
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Citation APA MLA Chicago Evaluated Gas Phase Basicities and Proton Affinities of Molecules : An Update. (n.d.). Evaluated Gas Phase Basicities and Proton Affinities of Molecules : An Update. Retrieved from http://gutenberg.cc/

Description
Technical Reference Publication

Table of Contents
Contents 1. Introduction.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 . I . Dedication to Professor Robert W. Taft. . . . . I .2. Background. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.3. Definitions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2. Sources of Proton AffinityIGas Basicity Data. . . . 2.1. Absolute Proton Affinity Values. . . . . . . . . . . 2.1.1. Ionization Threshold Measurements. . . 2.1 .I. Absolute Values of Proton Affinities from Quantum Chemical Calculations. 2.2. Relative Gas BasicityIProton Affinity Values. 7.2.1. Gas Phase Equilibrium Constant Data. 2.2.2. Relative Gas Basicities from Bracketing Experiments. . . . . . . . . . . . . 7.7.3. Relative Proton Affinity Data from the Kinetic Method. . . . . . . . . . . . . . 2.2.4. Relative Gas BasicityProton Affinity Data from the Thermokinetic Method. . . . . . . . . . . . . . . . . . . . . . . . . 1.2.5. Other Sources of Relative Proton Aftinit! Data.. . . . . . . . . . . . . . . . . . . . . 7.3. Kelnarks Conctrninp Tt.mpsrature Dependence of Proton .?\ftinities and Protonntlon kntroples.. . . . . . . . . . . . . . . . . . . . 3 . E\nli~;~tio01n' .Ab\olute Proton Aftinit~rsf ro111 lonlrat~onl 'hrr\hi~ld\ I~.a\uremcnts... . . . . . . . . . . .;.I. Kcten?: CHICO.. . . . . . . . . . . . . . . . . . . . . . . 3.2. I\ohurene: I CH:I :CCHI. . . . . . . . . . . . . . . . . .:.;. .Acc.taldeh>li t: CH:CHO. . . . . . . . . . . . . . . . . 3 . i . Pr,.rpene. CH,CHCH, .,I.> -. Form;ilileli! ile: CH.0. . . . . . . . . . . . . . . . . . 3.h. H!~lro?en \illtide: H;S. . . . . . . . . . . . . . . 3.7. \\',~rer: HIO. . . . . . . . . . . . . . . . . . . . . . 3.8. Ethene: CH,CH,. . . . . . . . . . . . . . . . . . 3.9. Carbon Monoxide: CO. . . . . . . . . . . . . . . . . . 3.10. Carbon Dioxide: CO,. . . . . . . . . . . . . . . . . . . 4. Evaluation of Thermodynamic Ladders. . . . . . . . . 5. Generation of the Scale of Absolute Proton Affinities from the Scale of Relative Gas Basicities. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.1. Evalua~ion or En~ropy Change Data. . . . . . . . 5.2. Procedures Followed in Evaluating Absolute Proton Affinities from the Scale of Relative Gas Basicities. . . . . . . . . . . . . . . . . . . . . . . . . . 5.3. Sample Evaluations. . . . . . . . . . . . . . . . . . . . . . 5.4. Uncertainty of the Proton Affinity Scale.. . . . 5.5. Problems Remaining. . . . . . . . . . . . . . . . . . . . . 6. Description of the Tables. . . . . . . . . . . . . . . . . . . . . 7. References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . List of Tables 1 . Gas basicity, proton affinity and protonation entropy of Hill sorted baaes.. . . . . . . . . . . . . . . . . . 429 2. Summary of proton transfer therl~~ochcmlccdil~ iia for each b;lse M. sorted by ?as basicity of M.. . . . 458 3. Annotated Reference5 to Tables 1 and 7. . . . . . . . 639